84650-91-9

Basic information

• Product Name: Pd(C₆H₅PPC₆H₅)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)
• CAS NO: 84650-91-9
• Molecular Weight: 721.003
• Mol File: 84650-91-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Pd(C₆H₅PPC₆H₅)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)(CAS DataBase Reference)
• NIST Chemistry Reference: Pd(C₆H₅PPC₆H₅)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)(84650-91-9)
• EPA Substance Registry System: Pd(C₆H₅PPC₆H₅)(P(C₆H₅)2CH₂CH₂P(C₆H₅)2)(84650-91-9)

Safety Data

• Hazardous Substances Data: 84650-91-9(Hazardous Substances Data)

Upstream product

• 19978-61-1 (1,2-bis(diphenylphosphanyl)ethane)dichloridopalladium(II) 
• 22789-32-8 1,2-dilithium-1,2-diphosphide 
• 19978-61-1 (1,2-bis(diphenylphosphino)ethane)palladium(II) chloride 

Downstream Products

• 94630-13-4 1-[1',2'-bis(diphenylphosphanyl)ethane]-2,2,2,2,2-pentacarbonyl-[(E)-μ-η-diphenyldiphosphene-P(Pd(1),W(2))P'(Pd(1))]-palladium(0)tungsten(0) 

Relevant articles and documents

THE NATURE OF THE Co-ORDINATE LINK. PART 11. SYNTHESIS AND PHOSPHORUS-31 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY OF PLATINUM AND PALLADIUM COMPLEXES CONTAINING SIDE-BONDED (E)-DIPHENYLDIPHOSPHENE. X-RAY CRYSTAL AND MOLECULAR STRUCTURES OF AND

The complexes cis- react with Li2(PhPPPh) to give .Complex (1) reacts with (thf= tetrahydrofuran) to give (2).Complexes were characterized by 31P-(1H) n.m.r. spectroscopy.X-ray crystal-structure determinations of complexes (1) and (2) reveal nearly identical and planar PdP4 mieties comprising the donor atoms of L2 and η2- ligands.In (2) the two diphosphene lone pairs co-ordinate to W(CO)5 groups and the W-P bonds are bent 32 deg away from the Pd atom.The diphosphene P-P bond in (2) is 0.06 angstroem longer than that in (1) , which is similar to that in other diphosphene complexes and is approxymately mid-way between the P-P single and double bond lengths.Small values of the coupling constants 1J(PtP) and 2J(PP) involving the diphosphene ligand indicate that the diphosphene uses electrons of low s character in η2-co-ordination.