846542-05-0

Basic information

• Product Name: (2'S,3'R,4S)-4-benzyl-3-[2'-benzyloxy-3'-(tert-butyldimethylsilanyloxy)-1'-hydroxybutyl]-5,5-dimethyloxazolidin-2-one
• Synonyms: (2'S,3'R,4S)-4-benzyl-3-[2'-benzyloxy-3'-(tert-butyldimethylsilanyloxy)-1'-hydroxybutyl]-5,5-dimethyloxazolidin-2-one
• CAS NO: 846542-05-0
• Molecular Weight: 513.75
• Mol File: 846542-05-0.mol

Chemical Properties

• CAS DataBase Reference: (2'S,3'R,4S)-4-benzyl-3-[2'-benzyloxy-3'-(tert-butyldimethylsilanyloxy)-1'-hydroxybutyl]-5,5-dimethyloxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (2'S,3'R,4S)-4-benzyl-3-[2'-benzyloxy-3'-(tert-butyldimethylsilanyloxy)-1'-hydroxybutyl]-5,5-dimethyloxazolidin-2-one(846542-05-0)
• EPA Substance Registry System: (2'S,3'R,4S)-4-benzyl-3-[2'-benzyloxy-3'-(tert-butyldimethylsilanyloxy)-1'-hydroxybutyl]-5,5-dimethyloxazolidin-2-one(846542-05-0)

Safety Data

• Hazardous Substances Data: 846542-05-0(Hazardous Substances Data)

Upstream product

• 496877-70-4 (S)-N-α-benzyloxyacetyl-4-benzyl-5,5-dimethyloxazolidin-2-one 
• 846542-02-7 (2'S,3'R,4S)-4-benzyl-3-(2'-benzyloxy-3'-hydroxybutyryl)-5,5-dimethyloxazolidin-2-one 
• 846542-03-8 (2'S,3'R,4S)-4-benzyl-3-[2'-benzyloxy-3'-(tert-butyldimethylsilanyloxy)butyryl]-5,5-dimethyloxazolidin-2-one 

Downstream Products

• 846542-06-1 (2S,3R)-2-benzyloxy-3-(tert-butyldimethylsilanyloxy)butyraldehyde 
• 846542-14-1 (2'S,3'S,4S,4'R,5'R)-4-benzyl-3-[2',4'-bis(benzyloxy)-5'-(tert-butyldimethylsilanyloxy)-3'-hydroxyhexanoyl]-5,5-dimethyloxazolidin-2-one 
• 846542-08-3 (2'R,3'S,4R,4'R,5'R)-4-benzyl-3-[2',4'-bis(benzyloxy)-5'-(tert-butyldimethylsilanyloxy)-3'-hydroxyhexanoyl]-5,5-dimethyloxazolidin-2-one 
• 846542-15-2 (3S,4R,5R,6R)-3,5-bis(benzyloxy)-4-hydroxy-6-methyltetrahydropyran-2-one 
• 846542-09-4 (3R,4S,5R,6R)-3,5-bis(benzyloxy)-4-hydroxy-6-methyltetrahydropyran-2-one 

Relevant articles and documents

A SuperQuat glycolate aldol approach to the asymmetric synthesis of hexose monosaccharides

A stereoselective two-carbon homologation protocol has been developed and applied to the asymmetric synthesis of the hexose monosaccharides D-galactose, D-fucose, D-idose, D-6-deoxyidose, D-talose and D-6-deoxytalose.