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Usage

Uses

Used in Coordination Chemistry:
4,4'-Bis[(1E)-2-[4-(hexyloxy)phenyl]ethenyl]-2,2'-bipyridine is used as a ligand in coordination chemistry for its ability to form stable complexes with metal ions. The presence of the bipyridine groups and the hexyloxy chains enhances the stability and solubility of the resulting metal complexes, making them suitable for various applications.
Used in Organic Synthesis:
In organic synthesis, 4,4'-Bis[(1E)-2-[4-(hexyloxy)phenyl]ethenyl]-2,2'-bipyridine serves as a versatile building block for the synthesis of a wide range of coordination and organometallic complexes. Its unique structure allows for the formation of various complex architectures, which can be further functionalized or modified to achieve desired properties and reactivities.
Used in Catalysis:
4,4'-Bis[(1E)-2-[4-(hexyloxy)phenyl]ethenyl]-2,2'-bipyridine is used as a ligand in catalytic applications due to its ability to form active metal complexes. The ethenyl group in its structure can participate in coordination with metal ions, facilitating catalytic reactions. The resulting metal complexes can be employed as catalysts in various organic transformations, such as oxidation, reduction, and coupling reactions.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, 4,4'-Bis[(1E)-2-[4-(hexyloxy)phenyl]ethenyl]-2,2'-bipyridine can be used as a starting material or intermediate in the synthesis of drug candidates. Its unique structure and the ability to form stable metal complexes make it a promising candidate for the development of novel therapeutic agents with potential applications in various diseases and conditions.
Used in Materials Science:
In materials science, 4,4'-Bis[(1E)-2-[4-(hexyloxy)phenyl]ethenyl]-2,2'-bipyridine can be utilized in the development of functional materials with specific properties. The formation of metal complexes with 4,4'-Bis[(1E)-2-[4-(hexyloxy)phenyl]ethenyl]-2,2'-bipyridine can lead to materials with unique optical, electronic, or magnetic properties, which can be applied in various technological applications, such as sensors, electronic devices, or energy storage systems.

Upstream product

• 5736-94-7 4-(hexyloxy)benzaldehyde 
• 176220-38-5 4,4'-bis(diethylphosphonomethyl)-2,2'-bipyridine 

Relevant academic research and scientific papers

Convenient synthesis of functionalized 4,4′-disubstituted-2,2′- bipyridine with extended π-system for dye-sensitized solar cell applications

Exploration of new ruthenium-based sensitizers for dye-sensitized solar cell (DSC) applications requires an easy access to multifunctionalized ligands for efficient screening of sensitizers' properties. Based on the Horner-Emmons-Wadsworth reaction, a convenient synthetic route for the extension of the π-system on 4,4′-disubstituted-2,2′-bipyridines was used to develop a novel series of functionalized 2,2′-bipyridine ligands with either electron-withdrawing or donating end-capping group. 1H NMR spectroscopy revealed that all the new bipyridyl ligands were obtained exclusively in their fully E isomers.

2,2-Bipyridine Ligand, Sensitizing Dye and Dye Sensitized Solar Cell

A dye sensitized solar cell, comprising a-heteroleptic polypyridil complex of Ru, Os or Fe. The donating ligand has an extended conjugated n-system increasing the light absorbance and keeing the LUMO energy level higher than that of the anchoring ligand. A compacting compound whose molecular structure comprises a terminal group, a hydrophobic part and an anchoring′ group may be co-adsorbed together with the dye on the semi-conductive metal oxide layer of the photoanode, forming a dense mixed self-assembled monolayer.