84662-06-6

Basic information

• Product Name: 2-Formyl-2-methyl-N-(4-nitrophenyl)propionothioamid
• Synonyms: 2-Formyl-2-methyl-N-(4-nitrophenyl)propionothioamid
• CAS NO: 84662-06-6
• Molecular Weight: 252.294
• Mol File: 84662-06-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Formyl-2-methyl-N-(4-nitrophenyl)propionothioamid(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Formyl-2-methyl-N-(4-nitrophenyl)propionothioamid(84662-06-6)
• EPA Substance Registry System: 2-Formyl-2-methyl-N-(4-nitrophenyl)propionothioamid(84662-06-6)

Safety Data

• Hazardous Substances Data: 84662-06-6(Hazardous Substances Data)

Upstream product

• 6906-32-7 N,N,2-Trimethyl-1-propen-1-amin 
• 2131-61-5 p-nitrophenyl isothiocyanate 
• 16826-16-7 N,N-Diethyl-2-methyl-1-propen-1-amin 

Relevant articles and documents

Cycloaddition Reactions of Heterocumulenes, XXVI. Cycloadducts from Aryl Isothiocyanates and 2,2-Disubstituted Enamines

Aryl isothiocyanates 1 react with enamines 2 to give two types of 2:1 cycloadducts.Below 50 deg C, 1a - g and 2 give rise to 6-imino-1,3-thiazine-2-thiones 5, the constitutions of which are proved by an X-ray analysis of 5c.Above 50 deg C or starting from 4-nitrophenyl isothiocyanate (1h), 2,4-dithiouracils 6 are formed. 1:1 cycloadducts of the reactants are detected spectroscopically; on workup, they hydrolyze to give 2-formylthiopropionanilides 9.