84700-47-0

Upstream product

• 84700-43-6 1-(2,6-dimethylphenyl)-1-acetoxy-2,2-dimethylpent-4-ene 
• 89329-73-7 (2aS,3aS,6S,6aS,6cS)-5,5,6b,6c-Tetramethyl-2a,3,3a,4,5,6,6b,6c-octahydro-cyclopenta[a]cyclopropa[gh]pentalen-6-ol 
• 84700-44-7 1-(2,6-Dimethyl-phenyl)-2,2-dimethyl-pent-4-en-1-ol 
• 576-22-7 2-Bromo-m-xylene 
• 84700-46-9 (3bS,6aS,7aS)-2,2,3b-Trimethyl-4-methylene-2,3b,4,6a,7,7a-hexahydro-1H-cyclopenta[a]pentalene 
• 108-98-5 thiophenol 

Downstream Products

• 84725-08-6 (3aR,3bR,4R,6aR,7aS)-4-Benzenesulfinylmethyl-2,2,3b-trimethyl-decahydro-cyclopenta[a]pentalene 
• 84700-48-1 (3aR,3bR,4R,6aR,7aS)-2,2,3b-Trimethyl-4-phenylsulfanylmethyl-decahydro-cyclopenta[a]pentalene 

Relevant academic research and scientific papers

SYNTHETIC STUDIES ON ARENE-OLEFIN CYCLOADDITIONS -III- TOTAL SYNTHESIS OF (+/-)-HIRSUTENE.

The arene-olefin meta-cycloaddition in show to provide a facile entry into linear tricyclopentanoid skeleta.Hirsutene is synthesized in seven steps by this method from 2,6-dimethylbromobenzene and 2,2-dimethylpent-4-enal.