847152-22-1Relevant academic research and scientific papers
Mono- and di-nuclear iridium(III) complexes. Synthesis and photophysics
Plummer, Edward A.,Hofstraat, Johannes W.,De Cola, Luisa
, p. 2080 - 2084 (2003)
This paper reports the synthesis and photophysical characterization of heteroleptic mono- and di-nuclear iridium(III) complexes. The complexes contain two ortho-metalating ligands, 2-phenylpyridine, with a bipyridine derivative as the third chelating unit. In the case of the dinuclear complexes the two iridium moieties are connected by a conjugated bridging ligand containing three or four phenyl units. All the complexes emit at room temperature and steady state and time resolved spectroscopy demonstrates that the lowest excited state is a metal-to-ligand charge transfer involving the bipyridine ligand. The Royal Society of Chemistry 2003.
Boronic acid-substituted metal complexes: Versatile building blocks for the synthesis of multimetallic assemblies
Arm, Kathryn J.,Williams, J. A. Gareth
, p. 230 - 232 (2007/10/03)
Polypyridyl complexes of Ru(n) and Ir(III) incorporating a boronic acid substituent undergo cross-coupling with bromosubstituted complexes, and a sequential coupling-bromination-coupling strategy permits the controlled synthesis of a luminescent Y-shaped heterometallic assembly, in which efficient energy transfer to the terminus occurs.
