847155-59-3Relevant academic research and scientific papers
Orthopalladacycles derived from α-diphenylhydrazonoketene dithioacetals and their reactivity with terminal alkynes
Ortega-Jiménez,López-Cortés,Ortega-Alfaro,Toscano,Penieres,Quijada,Alvarez
, p. 454 - 462 (2005)
In this paper, we present the synthesis and characterization of new orthopalladated complexes derived from α-diphenylhydrazonoketene dithioacetals. From their reaction with terminal alkynes, the intermediates of the expected Csp-Csp2coupling reaction were isolated in stable form and their structures were confirmed by X-ray diffraction studies.
