847225-17-6Relevant academic research and scientific papers
Reactions of bicyclo[2.2.1]hept-5-ene-2,3-dicarboximides with aromatic azides
Tarabara,Kas'yan,Yarovoi,Shishkina,Shishkin,Kas'yan
, p. 992 - 998 (2004)
Reactions of N-substituted bicyclo[2.2.1]hept-5-ene-endo-2,endo-3- dicarboximides with o- and p-nitrophenyl azides, as well as with p-nitrophenylsulfonyl azide and p-toluenesulfonyl azide, afforded the corresponding substituted dihydrotriazole (from aryl azides) and arylsulfonylaziridine derivatives (from sulfonyl azides). The exo orientation of the nitrogen-containing cyclic fragments (in keeping with the Alder rule) and endo orientation of the imide ring were confirmed by analysis of the IR and 1H and 13C NMR spectra. The molecular structure of one of the products was examined by X-ray analysis.
