847278-17-5Relevant academic research and scientific papers
Bimetallic complexes with porphyrins containing a cyclometalated phenylpyridine group
Cheung, Ka-Man,Zhang, Qian-Feng,Mak, Wing-Leung,Sung, Herman H.Y.,Williams, Ian D.,Leung, Wa-Hung
, p. 253 - 260 (2005)
Treatment of Ni(HP1) (H3P1 = meso-5-[4′-(2″-pyridyl)phenyl]-10,15,20-triphenyporphyrin) with K2[PdCl4] in EtOH afforded [Pd{Ni(P1)}] 2(μ-Cl)2 that reacted with NaS2CNEt 2 to give Pd(S2CNEt2)[Ni(P1)]. Reaction of Ni(HP1) with [Ir(H)2(PPh3) 2(Me2CO)2][BF4] afforded Ir(H)Cl(PPh3)2[Ni(P1)]. The crystal structures of Pd(S2CNEt2)[Ni(P1)] and Ir(H)(Cl)(PPh 3)2[Ni(P1)] have been determined.
