84736-06-1Relevant articles and documents
Chiral Cyclopentanoid Synthetic Intermediates via Asymmetric Microbial Reduction of Prochiral 2,2-Disubstituted Cyclopentanediones
Brooks, Dee W.,Grothaus, Paul G.,Irwin, William L.
, p. 2820 - 2821 (1982)
A prochiral distinction by microbial reduction of 2-propyl- (1), 2-allyl- (4), and 2-propynyl-2-methyl-1,3-cyclopentanedione (7) with bakers' yeast provides efficient access to several chiral cyclopentanoid synthetic intermediates.A short enantioselective
Asymmetric Microbial Reduction of Prochiral 2,2-Disubstituted Cycloalkanediones
Brooks, Dee W.,Mazdiyasni, Hormoz,Grothaus, Paul G.
, p. 3223 - 3232 (2007/10/02)
Asymmetric microbial reduction of a series of 2,2-disubstituted 1,3-cycloalkanediones with bakers' yeast was examined as an example of an enzyme-catalyzed distinction of a substrate containing two trigonal carbonyl centers with stereoheterotropic faces an
SYNTHETIC STUDIES OF TRICHOTHECENES, AN ENANTIOSELECTIVE SYNTHESIS OF A C-RING PRECURSOR OF ANGUIDINE
Brooks, Dee W.,Grothaus, Paul G.,Palmer, James T.
, p. 4187 - 4190 (2007/10/02)
An enantioselective synthesis of a cyclopentanoid C-ring precursor 19 of anguidine 3, a representative trichothecene with antitumor activity, from 2-allyl-2-methylcyclopentane-1,3-dione is described.
