84751-07-5

Upstream product

• 104957-43-9 K⁽¹⁺⁾*RuH(P(C₆H₅)3)2(C₆H₅(CH)4C₆H₅)^(1-)=K[RuH(P(C₆H₅)3)2(C₆H₅(CH)4C₆H₅)] 
• 84774-77-6 K⁽¹⁺⁾*RuH(P(C₆H₅)3)2(C₁₄H₁₀)^(1-)=K[RuH(P(C₆H₅)3)2(C₁₄H₁₀)] 
• 84774-77-6 K⁽¹⁺⁾*[HRu(P(C₆H₅)3)2(C₁₄H₁₀)]^(1-) = K[HRu(P(C₆H₅)3)2(C₁₄H₁₀)] 

Downstream Products

• 105007-74-7 K⁽¹⁺⁾*RuH₃(P(C₆H₅)3)2(CO)^(1-)=K[RuH₃(P(C₆H₅)3)2(CO)] 
• 84751-08-6 RuH₃(P(C₆H₅)3)2^(1-) 
• 84751-09-7 C₄₀H₃₇P₂Ru^(1-) 
• 105087-64-7 K⁽¹⁺⁾*RuH₃(P(C₆H₅)3)2^(1-)=K[RuH₃(P(C₆H₅)3)2] 
• 84774-77-6 K⁽¹⁺⁾*RuH(P(C₆H₅)3)2(C₁₄H₁₀)^(1-)=K[RuH(P(C₆H₅)3)2(C₁₄H₁₀)] 
• 84774-77-6 K⁽¹⁺⁾*[HRu(P(C₆H₅)3)2(C₁₄H₁₀)]^(1-) = K[HRu(P(C₆H₅)3)2(C₁₄H₁₀)] 
• 84751-10-0 RuH^(1-)*2P(C₆H₅)3*C₆H₈ = [HRu(P(C₆H₅)3)2(C₆H₈)]^(1-) 

Relevant academic research and scientific papers

HYDRIDO(PHOSPHINE)RUTHENATE COMPLEXES AND THEIR ROLE IN THE CATALYTIC HYDROGENATION OF ARENES

Starting with the potassium salt of (1), the following reactions in THF were identified: (1) 1+H2 -> fac-- (2); (2) 1+1,4-Ph2-1,3-butadiene -> - (3) + PPh3; (3) 3+4H2 -> - (4) + 1,4-Ph2-butane; (4) 4 + 1-hexene -> - (5) + hexane; (5) 4 + L -> - + H2 (L = CO, PPh3, PMe2Ph); (6) 2 + 1,5-anthracene (A) -> - (7) + 0.5 (1,2,3,4-H4A) + PPh3; (7) 4 + 5 C2H4 -> (8) + 3C2H6; (8) 4 + 2A -> 7 + 1,2,3,4-H4A; (9) 7 + 4H2 -> 4 + 1,2,3,4-H4A.Reactions 8 and 9 constitute a catalytic cycle for the hydrogenation of anthracene to 1,2,3,4-tetrahydroanthracene.