847670-53-5

Upstream product

• 500187-76-8 (1R,2R,3R,4R)-3-(4-methoxybenzyloxy)-2-((tert-butyl)dimethylsilyloxy)-1-(2-trimethylsilylethynyl)-4-vinylcyclobutanol 
• 500187-72-4 tert-Butyl-[(2R,3R,4R,5R)-2-methoxy-4-(4-methoxy-benzyloxy)-5-vinyl-tetrahydro-furan-3-yloxy]-dimethyl-silane 
• 500187-75-7 (1R,2S,3R,4S)-3-(4-methoxybenzyloxy)-2-((tert-butyl)dimethylsilyloxy)-4-vinylcyclobutanol 
• 500187-70-2 (2S,3R,4S,5R)-2-Methoxy-4-(4-methoxy-benzyloxy)-5-vinyl-tetrahydro-furan-3-ol 
• 620630-82-2 1,2 5,6-O-di(isopropylidene)-α-D-allofuranose 
• 205934-53-8 (3aR,5R,6R,6aR)-6-(4-methoxybenzyloxy)-2,2-dimethyl-5-vinyltetrahydrofuro[2,3-d][1,3]dioxole 
• 2746-25-0 p-Methoxybenzyl bromide 

Downstream Products

• 847670-54-6 (1S,2S,4S,5S)-3-(4-methoxybenzyloxy)cyclooctane-1,2,4,5-tetraol 

Relevant academic research and scientific papers

Enantioselective route from carbohydrates to cyclooctane polyols

(Chemical Equation Presented) A synthetic route to select cyclooctane-1,2,3-triols and 1,2,3,4,5-pentaols has been defined. The starting materials are D-glucose or D-arabinose, and the key steps consist of a zirconocene-promoted ring contraction, a [3,3]

From common carbohydrates to enantiopure cyclooctane polyols and glycomimetics via deoxygenative zirconocene ring contraction

D-Arabinose and D-glucose are transformed into the identical vinyl furanoside, whose role is to serve as the precursor to enantiopure cyclooctadienone 6. The key steps of this relay involve a zirconocene-promoted ring contraction and [3,3] sigmatropic rea