847672-38-2Relevant articles and documents
Enhanced dual visible light fluorescence from the 2,2′-dipyridyl tungsten alkylidyne complex [W(=CC6H4NMe 2-4)(O2CCF3)(CO)2{K 2-2,2′-(NC5H4)2}]: An organometallic twisted intramolecular charge transfer state
Jelliss, Paul A.,Wampler, Keith M.,Siemiarczuk, Aleksander
, p. 707 - 714 (2008/10/09)
The N,N-dimethylanilino tungsten alkylidyne complex [W(≡CC 6H4NMe2-4)CO2CCF3(CO) 2- (NC5H4Me-4)2] has been synthesized, characterized, and employed as a precursor to neutral and cationic 2,2′-dipyridyl and TMEDA (N,N,N,N-tetramethylethylenediamine) complexes, which display dual blue and yellow fluorescences in CH2Cl2 solutions at ambient temperatures with surprisingly high quantum yields for this class of organometallic complex. The efficiencies of the radiative emissions from the 2,2′-dipyridyl complex [W(≡CC6H 4NMe2- 4)(O2CCF3)(CO) 2{k2-2,2′-(NC5H4)2}] are particularly impressive. The dual nature of the emissions (λem ≈ 450 and 540-580 nm) is attributed to independent, short-lived (ns) twisted intramolecular charge transfer (1TICT) and 1dw-π*w-π*w=≡CAr states, respectively, the former being well understood in organic aromatic systems, but yet to be described for organometallic complexes.