847787-50-2Relevant academic research and scientific papers
Reactivity of phosphasilametallacyclopropane toward substrates with polarized E-H bonds (E = O, N, S, and P): Formation and structures of ring-opening products
Okazaki, Masaaki,Jung, Kyeong A.,Tobita, Hiromi
, p. 659 - 664 (2005)
Treatment of a three-membered metallacycle Cp*(CO)Fe{k 2(Si,P)-SiMe2PPh2} (1) with substrates of the type RnEH (ERn = OH, OMe, OiBu, OPh, S pTol, NEt2, NPhH, PPh2, and PPhH) results in the instantaneous formation of the ring-opening products Cp*(CO)Fe- (PPh2H)(SiMe2ERn). In these reactions, 1,2-additdon of the substrates occurs exclusively across the silicon-phosphorus bond in 1. The structures of the products have been unequivocally determined by spectroscopic data and X-ray diffraction analysis.
