847997-73-3

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Basic information

Product Name: (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE
Synonyms: (S,S)-1,1'-BIS[(S)-ALPHA-(DIMETHYLAMINO)-PHENYLMETHYL]-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE;(R,R)-(+)-2,2'-BIS[(S)-(N,N-DIMETHYLAMINO)(PHENYL)METHYL]-1,1'-BIS(DI(3,5-DIMETHYLPHENYL)PHOSPHINO)FERROCENE;MANDYPHOS SL-M009-2;(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE;(aS,aS)-1,1#-Bis[-(dimethylamino)benzyl]-(R,R)-2,2#-bis[di(3,5-xylyl)phos;(R,R)-(+)-2,2'-Bis[(S)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(di(3,5-dimethylphenyl)phosphino)ferrocene,min.97%;(s,s)-1,1'-bis[(s)-α-(dimethylamino)-phenylmethyl]-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene (acc to cas);(αs,αs)-1,1'-bis[α-(dimethylamino)benzyl]-(r,r)-2,2'-bis[di(3,5-xylyl)phosphino]ferrocene
CAS NO:847997-73-3
Molecular Formula: C60H66FeN2P2 10*
Molecular Weight: 932.97
EINECS: N/A
Product Categories: Chiral Phosphine;Ferrocene Series;Mandyphos Series
Mol File: 847997-73-3.mol
Article Data: 0

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: orange/Powder
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
Stability: store cold
CAS DataBase Reference: (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE(CAS DataBase Reference)
NIST Chemistry Reference: (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE(847997-73-3)
EPA Substance Registry System: (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE(847997-73-3)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany: 3
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 847997-73-3(Hazardous Substances Data)

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(R,R)-(+)-2,2'-bis[(S)-(n,N-dimethylamino(phenyl)methyl]-1,1'-bis(di(3,5-dimethylphenyl)phosphino)ferrocene
Cas No: 847997-73-3
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Dayang Chem (Hangzhou) Co.,Ltd.
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(R,R)-(+)-2,2'-Bis[(S)-(N,N-diMethylaMino)(phenyl)Methyl]-1,1'-bis(di(3,5-diMethylphenyl)phosphino)ferrocene, Min. 97%
Cas No: 847997-73-3
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(R)-(+)-2,2'-BIS[(S)-(N,N-DIMETHYLAMINO(PHENYL)METHYL]-1,1'-BIS(DI(3,5-DIMETHYLPHENYL)PHOSPHINO)FERROCENE
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Hangzhou Fandachem Co.,Ltd
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(R,R)-(+)-2,2'-Bis[(S)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(di(3,5-dimethylphenyl)phosphino)ferrocene
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HANGZHOU TIANYE CHEMICALS CO., LTD.
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(RP,R′P)-1,1′-Bis[(S)-α-(dimethylamino)benzyl]-2,2′-bis[di(3,5-xylyl)phosphino]ferrocene manufacturer
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Shanghai Yuanye Bio-Technology Co., Ltd.
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(ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]FERROCENE
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ZHEJIANG JIUZHOU CHEM CO.,LTD
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National Research Platform ISO 9001 CAS No. 847997-73-3
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Zhengzhou Kingorgchem Chemical Technology Co., Ltd.
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Best price/ (R,R)-(+)-2,2'-Bis[(S)-(N,N-diMethylaMino)(phenyl)Methyl]-1,1'-bis(di(3,5-diMethylphenyl)phosphino)ferrocene, Min. 97% CAS NO.847997-73-3
Cas No: 847997-73-3
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Jilin haofei import and export trade Co.,Ltd
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(R,R)-(+)-2,2'-Bis[(S)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(di(3,5-dimethylphenyl)phosphino)ferrocene, min. 97%
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Strem Chemicals, Inc.
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847997-73-3 Usage

Reactions

Ligand for Rh-catalyzed asymmetric hydrogenation of α-acetamidoacrylates. Ligand for Rh-catalyzed hydrogenation of α- and β-enamides, acrylic acid derivatives, itaconates, β-ketoesters and 1,3-diketones. Ligand for Rh-catalyzed asymmetric hydrogenation of furyl-substituted (Z)-dehydroamino acid derivatives. Ligand for Ir-catalyzed asymmetric transfer hydrogenation of ketones. Ligand for Cu-catalyzed enantioselective hydroboration of α- and β-unsaturated esters and nitriles.

Chemical Properties

Orange powder

General Description

sold in collaboration with Solvias AG

Check Digit Verification of cas no

The CAS Registry Mumber 847997-73-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,4,7,9,9 and 7 respectively; the second part has 2 digits, 7 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 847997-73:
(8*8)+(7*4)+(6*7)+(5*9)+(4*9)+(3*7)+(2*7)+(1*3)=253
253 % 10 = 3
So 847997-73-3 is a valid CAS Registry Number.

InChI:InChI=1/2C30H33NP.Fe/c2*1-21-15-22(2)18-26(17-21)32(27-19-23(3)16-24(4)20-27)29-14-10-13-28(29)30(31(5)6)25-11-8-7-9-12-25;/h2*7-20,30H,1-6H3;/t2*30-;/m00./s1

847997-73-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name	(R,R)-(+)-2,2'-Bis[(S)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(di(3,5-dimethylphenyl)phosphino)ferrocene, min. 97%

1.2 Other means of identification

Product number	-
Other names	MANDYPHOS SL-M009-2

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

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