84801-09-2Relevant articles and documents
Intramolecular addition reactions of functionalized arylcarbenes to double bonds
Kirmse, Wolfgang,H?mberger, Günter
, p. 3925 - 3934 (2007/10/02)
Arylcarbenes with unsaturated ortho substituents (vinyloxy, 1-propenyloxy, allyl, 2-butenyl, 2,4-pentadienyl) were generated in methanol by photolysis of diazo precursors. Intermolecular OH insertion was found to compete with intramolecular addition to th