84803-23-6Relevant academic research and scientific papers
Penultimate effect in the initiation of the cationic polymerization of isobutylene: Kinetic study of initiation with (3-chloro-1,1,3-trimethylbutyl)benzene
Kim, Moon Suk,Faust, Rudolf
, p. 5320 - 5322 (2002)
The rate constant of ionization of Cum-IB1-Cl was measured and compared with that of 2-chloro-2,4,4-trimethylpentane (TMPCl). Replacement of a methyl group in TMPCl with a phenyl group in Cum-IB1-Cl resulted in overall reactivity of
Scope and Limitations of Aliphatic Friedel-Crafts Alkylations. Lewis Acid Catalyzed Addition Reactions of Alkyl Chlorides to Carbon-Carbon Double Bonds
Mayr, Herbert,Striepe, Wilhelm
, p. 1159 - 1165 (2007/10/02)
Lewis acid catalyzed addition reactions of alkyl halides 1 with unsaturated hydrocarbons 2 have been studied. 1:1 addition products 3 are formed if the addends 1 dissociate faster than the corresponding products 3; otherwise, polymerization of 2 takes place.For reaction conditions under which 1 and 3 exist mainly undissociated, solvolysis constants of model compounds can be used to predict the outcome of any such addition reactions if systems with considerable steric hindrance are excluded.
