848032-09-7

Basic information

• Product Name: Benzamide, 2-(diphenylphosphino)-N,N-bis(1-methylethyl)-
• CAS NO: 848032-09-7
• Molecular Formula: C25H28NOP
• Molecular Weight: 389.477
• Mol File: 848032-09-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzamide, 2-(diphenylphosphino)-N,N-bis(1-methylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, 2-(diphenylphosphino)-N,N-bis(1-methylethyl)-(848032-09-7)
• EPA Substance Registry System: Benzamide, 2-(diphenylphosphino)-N,N-bis(1-methylethyl)-(848032-09-7)

Safety Data

• Hazardous Substances Data: 848032-09-7(Hazardous Substances Data)

Upstream product

• 20383-28-2 N,N-diisopropyl benzamide 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 1361946-57-7 C₂₇H₃₁AgNO₃P 
• 50777-76-9 (2-formylphenyl)(diphenyl)phosphine 

Relevant articles and documents

Aromatic amide-derived non-biaryl atropisomers as highly efficient ligands in silver-catalyzed asymmetric cycloaddition reactions

The synthesis of a series of aromatic amide-derived non-biaryl atropisomers with a phosphine group and multiple stereogenic centers is reported. The novel phosphine ligands exhibit high diastereo- and enantioselectivities (up to >99:1 d.r., 95-99% ee) as well as yields in the silver-catalyzed asymmetric [3+2] cycloaddition of aldiminoesters with nitroalkenes, which provides a highly enantioselective strategy for the synthesis of optically pure nitro-substituted pyrrolidines. In addition, the experimental results with regard to the carbon stereogenic center as well as the amide stereochemistry confirmed the potential of hemilabile atropisomers as chiral ligand in catalytic asymmetric [3+2] cycloaddition reaction.