84812-33-9Relevant articles and documents
Generation of Metal-Free Silyl Anions from Disilanes and Fluoride Catalyst. Synthetic Reactions with Aldehydes and 1,3-Dienes
Hiyama, Tamejiro,Obayashi, Michio,Mori, Ichiro,Nozaki, Hitosi
, p. 912 - 914 (2007/10/02)
The Si-Si bond of disilanes is found to be cleaved by tetrabutylammonium fluoride (TBAF) in hexamethylphosphoric triamide to produce metal-free silylanion and triorganosilyl fluoride.The disilane/TBAF reagent was studied spectrometrically.Sythetic application of the reagent with a catalytic amount of TBAF is illustrated by the reaction with aldehydes and 1,3-dienes.