84820-10-0Relevant academic research and scientific papers
On the [2,3] sigmatropic rearrangement of allylic nitro compounds
Alameda-Angulo, Celia,Quiclet-Sire, Beatrice,Schmidt, Elmar,Zard, Samir Z.
, p. 3489 - 3492 (2007/10/03)
(Chemical Equation Presented) Allylic nitro compounds undergo relatively clean [2,3] sigmatropic rearrangement upon heating in refluxing 1,2-dichlorobenzene in the presence of DABCO to give the corresponding allylic alcohols via the intermediate allylic n
TRIFLUOROACETOXY-PHENYLSELENATION OF NITROOLEFINS REGIOSELECTIVE PREPARATION OF NITROALLYLIC ALCOHOL DERIVATIVES AND THEIR USE AS MULTIPLE COUPLING REAGENTS
Seebach, Dieter,Calderari, Giorgio,Knochel, Paul
, p. 4861 - 4872 (2007/10/02)
It has been shown in previous papers that the pivalate of 2-nitro-2-propen-1-ol (NPP, 1), a nitroolefin with allylic leaving group, can be used as a versatile multiple coupling reagent.The present contribution describes the preparation of analogues, subst
SYNTHESIS AND REACTIONS OF SUBSTITUTED NITRO-ALLYLATING REAGENTS
Knochel, Paul,Seebach, Dieter
, p. 3897 - 3900 (2007/10/02)
Nitro-cyclohexenylation and α-phenyl-nitro-allylation of nucleophilic centres are achieved (see 11-16) whith the nitroallyl pivalates 2 and 5, and with the chloride 3, which are in turn prepared from the diols 9 and 10, respectively.
