84871-08-9Relevant articles and documents
Marine sterols. XII. Glaucasterol, a novel C27 sterol with a unique side chain, from the soft coral Sarcophyton glaucum
Kobayashi,Mitsuhashi
, p. 665 - 672 (1982)
A minor C27 sterol, glaucasterol, was isolated from the soft coral Sarcophyton glaucum. Based on the spectroscopic evidence and the correlation to cholestanol and 26-nor-27-homocholestanol, its structure was proposed to be 24ξ,25ξ-24,26-cyclocholesta-5,22E-dien-3β-ol (1), the first example of a natural C27 sterol having a cyclopropane ring in the side chain.
ISOLATION OF 5α,6-DIHYDROGLAUCASTEROL, A NEW MARINE C27 STEROL WITH A 24,26-CYCLIZED SIDE CHAIN, FROM THE SOFT CORAL SARCOPHYTON GLAUCUM
Kobayashi, Masaru,Ishizaka, Takashi,Mitsuhashi, Hiroshi
, p. 1803 - 1805 (2007/10/02)
A new marine C27 sterol was isolated from the soft coral Sarcophyton glaucum.Based on the spectroscopic evidence and the correlation to cholestanol and 26-nor-27-homocholestanol, its structure was proposed to be 24ξ,25ξ-24,26-cyclo-5α-cholest-22E-en-3β-ol (5α,6-dihydroglaucasterol, 1).KEYWORDS --- 24ξ,25ξ-24,26-cyclo-5α-cholest-22E-en-3β-ol; 5α,6-dihydroglaucasterol; Sarcophyton glaucum; Alcyonaceae; Coelenterata