848737-98-4

Upstream product

• 335060-49-6 (2S,4R)-5-{[(1,1-dimethylethyl)(dimethyl)silyl]oxy}-2,4-dimethylpentyl acetate 
• 147782-81-8 (2S,4R)-1-<(tert-Butyldimethylsilyl)oxy>-2,4-dimethylpentanal 
• 147782-80-7 (2S,4R)-5-(tert-butyl(dimethyl)silyloxy)-2,4-dimethyl-1-pentanol 
• 90270-02-3 (2R,4S)-1-hydroxy-2,4-dimethylpentyl acetate 
• 848737-96-2 (4S,5R)-5-[(1S,3R)-4-(tert-Butyl-dimethyl-silanyloxy)-1,3-dimethyl-butyl]-2-phenyl-[1,3]dioxolane-4-carboxylic acid ethyl ester 
• 848737-88-2 (2R,3R,4S,6R)-3-benzyloxy-7-(t-butyldimethylsilyloxy)-4,6-dimethyl-1,2-heptanediol 
• 848737-86-0 (2R,3R,4S,6R)-7-(t-butyldimethylsilyloxy)-2,3-benzylidendioxy-4,6-dimethyl-1-heptanol 
• 848737-84-8 (2S,3R,4S,6R)-ethyl 7-(t-butyldimethylsilyloxy)-2,3-dihydroxy-4,6-dimethylheptanoate 
• 848737-82-6 ethyl (2E,4S,6R)-7-[1-(tert-butyl)-1,1-dimethylsilyl]oxy-4,6-dimethyl-2-heptenoate 
• 848737-97-3 [(2R,4S,5R)-5-Benzyloxy-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,4-dimethyl-pentyloxy]-tert-butyl-dimethyl-silane 

Downstream Products

• 848737-91-7 (2R,3R,4S,6R,8E)-3-benzyloxy-1,2-isopropylidendioxy-4,6,8-trimethyl-8-decene 
• 848737-90-6 (2R,3R,4S,6R)-3-benzyloxy-7-iodo-1,2-isopropylidendioxy-4,6-dimethylheptane 

Relevant academic research and scientific papers

Total synthesis of TT-1 (rasfonin), an α-pyrone-containing natural product from a fungus Trichurus terrophilus

Total synthesis of TT-1 (1=rasfonin), an α-pyrone-containing natural product from a Fungi Imperfecti Trichurus terrophilus culture was achieved by a stereoselective method in optically active form, which further provided evidence for the whole structure of TT-1 (1) including the absolute stereochemistry.