848872-98-0Relevant articles and documents
Enantioselective radical addition/trapping reactions with α,β-disubstituted unsaturated imides. Synthesis of anti-propionate aldols
Sibi, Mukund P.,Petrovic, Goran,Zimmerman, Jake
, p. 2390 - 2391 (2007/10/03)
This manuscript describes a highly diastereo- and enantioselective intermolecular radical addition/hydrogen atom transfer to α,β-disubstituted enoates. Additionally, we show that anti-propionate aldol-like products can be easily prepared from α-methyl-β-acyloxyenoates in good yields and high diastereo- and enantioselectivities. Copyright