848899-39-8

Upstream product

• 123914-19-2 1-(N,N-dimethylsulfamoyl)-2-phenylthio-1H-imidazole 
• 848899-43-4 2-phenylthio-5-(3-phthalimidopropyl)-1-(N,N-dimethylsulfamoyl)imidazole 
• 848899-34-3 2-phenylthio-5-(3-chloropropyl)-1-(N,N-dimethylsulfamoyl)imidazole 
• 50371-52-3 4,5-dibromopyrrol-2-yl trichloromethyl ketone 
• 6940-76-7 1-iodo-3-chloro-propane 
• 848899-36-5 2-phenylthio-5-(3-chloropropyl)-1-(N,N-dimethylsulfamoyl)imidazole 

Relevant academic research and scientific papers

Extending pummerer reaction chemistry. Synthesis studies in the phakellin alkaloid area

(Chemical Equation Presented) The syntheses of (±)- dibromophakellstatin and, from this species, (±)-dibromophakellin are described. Oxidative cyclization of a phenylthiolated dihydrooroidin derivative triggered by a Pummerer reaction constitutes the key

Extending pummerer reaction chemistry. Synthesis of (±)- dibromophakellstatin by oxidative cyclization of an imidazole derivative

(Chemical Equation Presented) The diastereoselective oxidative cyclization of a dihydrooroidin derivative is reported. The thioimidate product formed by application of a new variant of the Pummerer reaction serves as a precursor to dibromophakellstatin.