849096-89-5Relevant academic research and scientific papers
Simple, mild and efficient thioacetalization and transthioacetalization of carbonyl compounds and deprotection of thioacetals: Unique role of thiols in the selectivity of thioacetalization
Das, Biswanath,Ramu, Ravirala,Reddy, Majjigapu Ravinder,Mahender, Gurram
, p. 250 - 254 (2005)
Silica supported sodium hydrogen sulfate (NaHSO4·SiO 2) has been employed for efficient thioacetalization and transthioacetalization of carbonyl compounds in CH2Cl2 at room temperature. Selectivity of thioacetalization was dependent on the thiols used for the conversion. The same catalyst was also found to be effective for deprotection of thioacetals in CH2Cl2-H2O at room temperature.
