849100-77-2Relevant academic research and scientific papers
Synthesis of novel dendrimeric systems containing NLO ligands
Brouwer, Arwin J.,Liskamp, Rob M. J.
, p. 487 - 495 (2007/10/03)
The convergent synthesis of novel dendrimeric systems containing NLO-ligands is described. The poor solubility properties of dendrimers of type A containing NLO-ligands enticed us into developing novel dendrimers of type B leading to the convergent synthesis of third generation NLO-containing dendrimer 15 containing branches of unequal length. Furthermore, a strategy was developed for connection of dendrons leading to dendrimer-to-dendrimer systems of type C. For this a dendrimer was required of which selectively one branch could be deprotected i.e. dendrimer 22. To the deprotected branch a next dendrimer moiety was attached leading to 23, also containing a deprotectable branch, which was used for attachment of another dendrimer moiety, leading to dendrimer-to- dendrimer system 24. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005.
