849407-23-4Relevant academic research and scientific papers
Synthesis of [2Fe-2S] and [4Fe-4S] clusters having terminal amide ligands from an iron(II) amide complex
Ohki, Yasuhiro,Sunada, Yusuke,Tatsumi, Kazuyuki
, p. 172 - 173 (2005)
The reaction of iron(II) bis-amide Fe{N(SiMe3)2} 2 with elemental sulfur afforded a direct entry to new [Fe 2S2] and [Fe2S4] clusters with terminal amide groups, Fe4S4{N(SiMe3) 2}4 (1) and Fe2S2{N(SiMe 3)2}2(tmtu)2 (2), whose structures have been determined by X-ray crystallography. Tetrameric cubane cluster 1 exhibits one reversible and one quasireversible processes in the cyclic voltammetry, whereas dimeric rhombus complex 2 reveals one irreversible reduction process. Copyright
