84956-79-6Relevant academic research and scientific papers
CiF bond activation of unactivated aliphatic fluorides: Synthesis of fluoromethyl-3,5-diaryl-2-oxazolidinones by desymmetrization of 2-aryl-1,3-difluoropropan-2-ols
Haufe, Guenter,Suzuki, Satoru,Yasui, Hiroyuki,Terada, Chisato,Kitayama, Takashi,Shiro, Motoo,Shibata, Norio
, p. 12275 - 12279 (2012)
How to lose fluorine: Biologically relevant oxazolidinones 1 were synthesized through the desymmetrization of unactivated aliphatic difluorides by Si-induced catalytic CiF bond-cleavage using BSA/CsF (BSA=bis(trimethylsilyl) acetamide). The direct transfo
