849619-42-7Relevant articles and documents
Stereoselective glycosylation reactions with chiral auxiliaries
Kim, Jin-Hwan,Yang, Hai,Boons, Geert-Jan
, p. 947 - 949 (2005)
Good neighbors: A chiral auxiliary is used for the first time to control the anomeric selectivity of glycosylation reactions. In this approach, upon treatment with an activator A+, neighboring-group participation pation of an (S)-ethoxycarbonyl
Stereoselective glycosylations using (R)- or (S)-(ethoxycarbonyl)benzyl chiral auxiliaries at C-2 of glycopyranosyl donors
Kim, Jin-Hwan,Yang, Hai,Khot, Vishal,Whitfield, Dennis,Boons, Geert-Jan
, p. 5007 - 5028 (2007/10/03)
The stereoselective introduction of a glycosidic bond presents the greatest challenge to complex oligosaccharide synthesis. Important developments such as automated polymer-supported oligosaccharide synthesis will not realize their full potential until th
A general strategy for stereoselective glycosylations
Kim, Jin-Hwan,Yang, Hai,Park, Jin,Boons, Geert-Jan
, p. 12090 - 12097 (2007/10/03)
The principal challenge that the synthesis of oligosaccharides of biological importance presents is the development of a general approach for the stereoselective introduction of a glycosidic linkage. It is shown here that a (1S)-phenyl-2-(phenylsulfanyl)e