849728-32-1

Basic information

• Product Name: Carbamic acid, methyl[2-(phenylethenylidene)hexyl]-, 1,1-dimethylethyl ester
• CAS NO: 849728-32-1
• Molecular Formula: C20H29NO2
• Molecular Weight: 315.456
• Mol File: 849728-32-1.mol

Chemical Properties

• CAS DataBase Reference: Carbamic acid, methyl[2-(phenylethenylidene)hexyl]-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, methyl[2-(phenylethenylidene)hexyl]-, 1,1-dimethylethyl ester(849728-32-1)
• EPA Substance Registry System: Carbamic acid, methyl[2-(phenylethenylidene)hexyl]-, 1,1-dimethylethyl ester(849728-32-1)

Safety Data

• Hazardous Substances Data: 849728-32-1(Hazardous Substances Data)

Upstream product

• 7541-17-5 tert-butyl N,N-dimethylcarbamate 

Relevant articles and documents

Reaction of α-(N-carbamoyl)alkylcuprates with propargyl substrates: Synthetic route to α-amino allenes and Δ3-pyrrolines

(Chemical Equation Presented) Carbamate deprotonation followed by treatment with CuCN·2LiCl affords α-(N-carbamoyl)-alkylcuprates which react with propargyl halides, mesylates, tosylates, phosphates, acetates, and epoxides to give α-(N-carbamoyl) allenes via an anti-SN2′ substitution process. Propargyl halides, sulfonates, and phosphates give good yields of carbamoyl allenes, while the acetates afford low yields. Propargyl substrates undergo regiospecific SN2′ substitution in the absence of severe steric hindrance. The α-(N-carbamoyl) allenes can be cyclized to 2-oxazolidinones or deprotected to afford the free amines which can be cyclized to Δ3-pyrrolines with either AgNO3 or Ru3(CO)12.