849753-57-7Relevant academic research and scientific papers
Asymmetric exchange of cyclopalladated ligands: A new route to optically active phosphapalladacycles
Dunina,Gorunova,Kuznetsova,Turubanova,Livantsov,Grishin,Kuz'mina,Churakov
, p. 2193 - 2211 (2008/10/09)
An asymmetric version of the cyclopalladated ligand exchange reaction was developed. This procedure involves the use of prochiral phosphines in an aprotic medium. A benzylaminate palladacycle bearing the primary amino group and the bulky But substituent at the C*stereo-center serves as a chirality inductor. Springer Science+Business Media, Inc. 2006.
A straight forward in situ preparation of NHC-substituted phosphapalladacycles
Frey, Guido D.,Schütz, Jan,Herrmann, Wolfgang A.
, p. 2403 - 2408 (2007/10/03)
A new simple technique for the preparation of NHC-substituted phosphapalladacycles is reported by using phosphapalladacycle acetate precursors and azolium tetrafluoroborate salts in DMSO. The one-pot synthesis avoids multi-step reactions employing free ca
