84978-89-2

Upstream product

• 58713-52-3 2'-methoxy-5,6-dihydro-[1,1'-biphenyl]-3(4H)-one 
• 5323-87-5 3-Ethoxycyclohex-2-en-1-one 
• 31600-86-9 2-methoxyphenyllithium 

Downstream Products

• 84978-93-8 4a-(2-Methoxy-phenyl)-2-methyl-1,4,4a,5,6,8a-hexahydro-2H-isoquinolin-3-one 
• 84978-92-7 2-[1-(2-Methoxy-phenyl)-cyclohex-2-enyl]-N-methyl-acetamide 
• 84978-91-6 [1-(2-Methoxy-phenyl)-cyclohex-2-enyl]-acetic acid 
• 84978-90-5 [1-(2-Methoxy-phenyl)-cyclohex-2-enyl]-acetic acid ethyl ester 

Relevant academic research and scientific papers

A NEW AND FACILE STEREOSELECTIVE SYNTHESIS OF CIS-4a-ARYL-1,2,3,4,4a,5,6,8a-OCTAHYDROISOQUINOLINE DERIVATIVES

Cis-1,2,3,4,4a,5,6,8a-octahydro-2-methyl-4a-phenylisoquinolin-3-one was obtained by cyclization of the acyliminium ion intermediate, derived from the corresponding amide.Reduction of this cyclization product with LiAlH4 in THF afforded cis-1,2,3,4,4a,5,6,8a-octahydro-2-methyl-4a-phenylisoquinoline.In a similar way, the octahydro-4a-(2-methoxyphenyl)-isoquinolin-3-one was also prepared from the corresponding amide.