849796-05-0

Basic information

• Product Name: 2-Propenal, 3-(pentafluorophenyl)-, (2E)-
• CAS NO: 849796-05-0
• Molecular Formula: C9H3F5O
• Molecular Weight: 222.114
• Mol File: 849796-05-0.mol

Chemical Properties

• CAS DataBase Reference: 2-Propenal, 3-(pentafluorophenyl)-, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenal, 3-(pentafluorophenyl)-, (2E)-(849796-05-0)
• EPA Substance Registry System: 2-Propenal, 3-(pentafluorophenyl)-, (2E)-(849796-05-0)

Safety Data

• Hazardous Substances Data: 849796-05-0(Hazardous Substances Data)

Upstream product

• 653-37-2 perfluorobenzaldehyde 
• 2136-75-6 (triphenylphosphoranylidene)acetaldehyde 
• 1736-60-3 1-allyl-2,3,4,5,6-pentafluorobenzene 

Downstream Products

• 849796-16-3 (1E,3S)-1-pentafluorophenylhexa-1,5-dien-3-ol 
• 56693-03-9 1,2,3,4,5-pentafluoro-6-[(1E,3E)-4-phenyl-1,3-butadien-1-yl]benzene 
• 849796-25-4 2,2,2-trichloro-N-[(1S,2E)-1-pentafluorophenylhexa-2,5-dienyl]acetamide 
• 1013421-30-1 3-(perfluorophenyl)-2-phenylisoxazolidin-5-one 

Relevant articles and documents

Regioselective α-Deuteration of Michael Acceptors Mediated by Isopropylamine in D2O/AcOD

Site-specific hydrogen/deuterium exchange is an important method to access deuterated compounds for chemical and biological studies. Herein is reported the first method for the regioselective α-deuteration of enals and enones. The transformation features D2O and AcOD as deuterium sources and amines as organocatalysts. The deuteration strategy is scalable and works on enals with a variety of substituted arene or heterocycle motifs as well as enones. The method has been applied to the synthesis of deuterated drug precursors.

Palladium-catalyzed allylic C-H oxidation under simple operation and mild conditions

We discovered an effective and simple system (Pd/BQ/air/r.t.) for making allylic alcohols through Pd-catalyzed allylic C-H bond functionalization. This approach exhibits advantages due to its simple operation, mild conditions, and environmentally benign features. By modifying reaction conditions, it can be suitable for preparing unsaturated aldehydes, allylic esters, ethers, and amines.

CARBOLINE ANTIPARASITICS

The present invention provides Formula (1 ) compounds that are gamma-carbolines, Formula (1) wherein R1 a, R1 b, R1 c, R1d, R2, R3, and "— " are as defined herein; veterinary acceptable salts thereof, and stereoisomers thereof, which act as parasiticides,

Asymmetric allylboration of α,β-enals as a surrogate for the enantioselective synthesis of allylic amines and α-amino acids

(Chemical Equation Presented) Optically pure allylic amines have been synthesized from α,β-unsaturated aldehydes via allylboration with (-)-B-allyldiisopinocampheylborane, followed by Overman rearrangement. By incorporating crotyl and alkoxyallylboration, functionalization at δ-position was readily accomplished. By applying this methodology, the synthesis of several chiral α-amino acids has been achieved.

Regiospecific photoisomerization of fluorinated (E,E)-1,4-diphenyl-1,3- butadienes

Photoisomerization of five fluorinated E,E-1-(R-phenyl)-4-phenyl-1,3- butadienes in solution (R = 1: p-monofluoro, 2: m,m′-difluoro, 3: m,m′,p-trifluoro, 4: o,o′,m,m′-tetrafluoro, 5: o,o′,m,m′,p-pentafluoro) was investigated via direct irradiation. Our results indicated that cis-trans photoisomerization of the fluorinated 1,4-diphenyl-1,3-butadienes in the excited singlet state took place exclusively at the CC bonds closer to the fluorine substituents.