85008-19-1

Basic information

• Product Name: (R)-1-((S)-2-Phenyl-hexahydro-pyrrolo[1,2-c]imidazol-3-yl)-propan-1-ol
• CAS NO: 85008-19-1
• Molecular Weight: 246.352
• Mol File: 85008-19-1.mol

Chemical Properties

• CAS DataBase Reference: (R)-1-((S)-2-Phenyl-hexahydro-pyrrolo[1,2-c]imidazol-3-yl)-propan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-((S)-2-Phenyl-hexahydro-pyrrolo[1,2-c]imidazol-3-yl)-propan-1-ol(85008-19-1)
• EPA Substance Registry System: (R)-1-((S)-2-Phenyl-hexahydro-pyrrolo[1,2-c]imidazol-3-yl)-propan-1-ol(85008-19-1)

Safety Data

• Hazardous Substances Data: 85008-19-1(Hazardous Substances Data)

Upstream product

• 71350-58-8 3-methoxycarbonyl-2-phenyl-hexahydro-1H-pyrrolo[1,2-c]imidazole 
• 74-96-4 ethyl bromide 
• 84994-56-9 2-Phenyl-hexahydro-pyrrolo[1,2-c]imidazole-3-carbaldehyde 

Downstream Products

• 89279-49-2 2-(benzyloxy)butanal 

Relevant articles and documents

AN ASYMMETRIC SYNTHESIS OF α-BENZYLOXY ALDEHYDES HAVING A CHIRAL TERTIARY CENTER - AN APPLICATION TO THE ASYMMETRIC SYNTHESIS OF exo-(+)-BREVICOMIN -

α-benzyloxy aldehydes having a chiral tertiary center at α-carbon atom are synthesized in high enantiomeric excess by successive treatment of 2-methoxycarbonyl-3-phenyl-1,3-diazabicyclooctane with diisobutylaluminum hydride (DIBAL-H) and Grignard reagents.The asymmetric reaction is applied to the total synthesis of exo-(+)-brevicomin.