850161-08-9

Basic information

• Product Name: (4RS)-3-(tert-butoxy)-4-hydroxy-2-methyl-4-{(3R,6S)-6-methyl-3-[(2S,4E)-2-methyl-4,6-heptadien-2-yl]-1-cyclohexenyl}-2-cyclobuten-1-one
• Synonyms: (4RS)-3-(tert-butoxy)-4-hydroxy-2-methyl-4-{(3R,6S)-6-methyl-3-[(2S,4E)-2-methyl-4,6-heptadien-2-yl]-1-cyclohexenyl}-2-cyclobuten-1-one
• CAS NO: 850161-08-9
• Molecular Weight: 372.548
• Mol File: 850161-08-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4RS)-3-(tert-butoxy)-4-hydroxy-2-methyl-4-{(3R,6S)-6-methyl-3-[(2S,4E)-2-methyl-4,6-heptadien-2-yl]-1-cyclohexenyl}-2-cyclobuten-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4RS)-3-(tert-butoxy)-4-hydroxy-2-methyl-4-{(3R,6S)-6-methyl-3-[(2S,4E)-2-methyl-4,6-heptadien-2-yl]-1-cyclohexenyl}-2-cyclobuten-1-one(850161-08-9)
• EPA Substance Registry System: (4RS)-3-(tert-butoxy)-4-hydroxy-2-methyl-4-{(3R,6S)-6-methyl-3-[(2S,4E)-2-methyl-4,6-heptadien-2-yl]-1-cyclohexenyl}-2-cyclobuten-1-one(850161-08-9)

Safety Data

• Hazardous Substances Data: 850161-08-9(Hazardous Substances Data)

Upstream product

• 124175-62-8 3-(tert-butoxy)-4-methyl-cyclobut-3-ene-1,2-dione 
• 850161-12-5 (2S,5S)-2-methyl-5-[(2S,4Z)-6-methyl-4,6-heptadien-2-yl]cyclohexan-1-one 
• 850161-06-7 (2S,5S)-2-methyl-5-[(2S,4E)-6-methyl-4,6-heptadien-2-yl]cyclohexan-1-one 

Relevant articles and documents

Total synthesis of (-)-colombiasin A and (-)-elisapterosin B

Intramolecular cycloaddition reactions are central in the total syntheses of colombiasin A (1) and elisapterosin B (2) described, which use (-)-dihydrocarvone as the starting material. A Moore rearrangement of a vinylcyclobutene is used to initiate the cycloaddition.