85020-99-1

Basic information

• Product Name: methyl α-phenylthiobut-2-enoate
• Synonyms: methyl α-phenylthiobut-2-enoate
• CAS NO: 85020-99-1
• Molecular Weight: 208.281
• Mol File: 85020-99-1.mol

Chemical Properties

• CAS DataBase Reference: methyl α-phenylthiobut-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl α-phenylthiobut-2-enoate(85020-99-1)
• EPA Substance Registry System: methyl α-phenylthiobut-2-enoate(85020-99-1)

Safety Data

• Hazardous Substances Data: 85020-99-1(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 3196-15-4 Methyl 2-bromobutyrate 
• 623-43-8 crotonic acid methyl ester 
• 662110-11-4 (E)-methyl 3-nitrobut-2-enoate 

Downstream Products

• 131010-99-6 (S)-3-{(S)-3-[1-Butylsulfanyl-meth-(E)-ylidene]-1-methyl-2-oxo-cyclopentyl}-2-phenylsulfanyl-butyric acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester 
• 131010-98-5 (Z)-2-Phenylsulfanyl-but-2-enoic acid (1R,2S,5R)-5-methyl-2-(1-methyl-1-phenyl-ethyl)-cyclohexyl ester 
• 128098-87-3 (E)-(5RS,6RS)-5,7-dimethyl-4,6,7-tris(phenylthio)oct-2-ene 
• 128098-82-8 (3RS,4RS)-2,4-dimethyl-3,5,5-tris(phenylthio)octan-2-ol 
• 128134-35-0 (2RS,3RS)-3-methyl-2,4,4-tris(phenylthio)heptan-1-ol 
• 128098-70-4 (2S,3R)-3-Methyl-2,4,4-tris-phenylsulfanyl-heptanoic acid methyl ester 
• 128098-70-4 methyl (2RS,3RS)-3-methyl-2,4,4-tris(phenylthio)heptanoate 
• 97125-56-9 (Z)-2-(phenylsulfanyl)but-2-enoic acid 
• 131011-00-2 (S)-3-{(S)-3-[1-Butylsulfanyl-meth-(E)-ylidene]-1-methyl-2-oxo-cyclopentyl}-2-phenylsulfanyl-butyric acid methyl ester 

Relevant articles and documents

Nucleophilic α-addition to β-nitroacrylates: application to the synthesis of α-thioacrylates

The α-addition of alkyl or aryl thionucleophiles to β-nitro-α,β-unsaturated alkenoates in THF in the presence of TEA or DBU gave access to the α-thio-α,β-unsaturated alkenoates. The reaction occurred via formation of β-nitro-α-thioalkanoates and concomitant elimination of nitrous acid from the α-adducts.

Direct benzothiophene formation via oxygen-triggered intermolecular cyclization of thiophenols and alkynes assisted by manganese/PhCOOH

An intermolecular oxidative cyclization between thiophenols and alkynes for benzothiophene formation has been established. A variety of multifunctional benzothiophenes are synthesized. In addition, we demonstrated that the obtained benzothiophenes can be