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85028-02-0

2-methylcyclopentanone oxime tosylate is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 85028-02-0 Structure

  • Basic information

    1. Product Name: 2-methylcyclopentanone oxime tosylate
    2. Synonyms: 2-methylcyclopentanone oxime tosylate
    3. CAS NO:85028-02-0
    4. Molecular Formula:
    5. Molecular Weight: 267.349
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 85028-02-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 2-methylcyclopentanone oxime tosylate(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2-methylcyclopentanone oxime tosylate(85028-02-0)
    11. EPA Substance Registry System: 2-methylcyclopentanone oxime tosylate(85028-02-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 85028-02-0(Hazardous Substances Data)

85028-02-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 85028-02-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,5,0,2 and 8 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 85028-02:
(7*8)+(6*5)+(5*0)+(4*2)+(3*8)+(2*0)+(1*2)=120
120 % 10 = 0
So 85028-02-0 is a valid CAS Registry Number.

85028-02-0Downstream Products

85028-02-0Relevant articles and documents

Organoaluminum-Promoted Beckmann Rearrangement of Oxime Sulfonates

Maruoka, Keiji,Miyazaki, Tohru,Ando, Mamoru,Matsumura, Yasushi,Sakane, Soichi,et al.

, p. 2831 - 2843 (2007/10/02)

The Beckmann rearrangement of oxime sulfonates with simultaneous nucleophilic trapping of the intermediary iminocarbocation by organoaluminum reagents is described.This process provides a new and highly efficient route to imino thioethers, imino selenoethers, imino nitriles, and α-alkylated amines starting from oxime sulfonates by the use of dialkylaluminum thiolates, selenolates, diethylaluminum chloride-trimethylsilyl cyanide, and trialkylaluminum-diisobutylaluminum hydride systems, respectively.The present organoaluminum-promoted Beckmann rearrangement of oxime sulfonates has been successfully applied to the synthesis of naturally occuring alkaloids, pumiliotoxin C and solenopsin A and B, in stereoselective fashion.Moreover, α,α-dialkylation of amines can be realized by the successive treatment of oxime sulfonates with trialkylaluminum followed by allylic or propargylic Grignard reagents in synthetically useful yields.

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