850446-94-5

Basic information

• Product Name: 1,3-bis(trimethylsilyl)-2-phenoxy-1,3,2-diazabora-[3]-ferrocenophane
• CAS NO: 850446-94-5
• Molecular Weight: 462.33
• Mol File: 850446-94-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3-bis(trimethylsilyl)-2-phenoxy-1,3,2-diazabora-[3]-ferrocenophane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-bis(trimethylsilyl)-2-phenoxy-1,3,2-diazabora-[3]-ferrocenophane(850446-94-5)
• EPA Substance Registry System: 1,3-bis(trimethylsilyl)-2-phenoxy-1,3,2-diazabora-[3]-ferrocenophane(850446-94-5)

Safety Data

• Hazardous Substances Data: 850446-94-5(Hazardous Substances Data)

Upstream product

• 75088-70-9 (phenyloxy)dichloroborane 

Relevant articles and documents

Novel 1,3,2-diazabora-[3]ferrocenophanes and a 1,4,2,3-diazadibora-[4] ferrocenophane

N,N′-Dilithiated 1,1′-bis(trimethylsilylamino)ferrocene (2) reacts with boron halide adducts (HBBr2-SMe2; BF 3-OEt2 and BBr3-SMe2), boron halides (BCl3, BBr3, BCl2(OPh) and BCl 2(Ph)) and 1,1-bis(dimethylamino)dichlorodiborane(4) to give the corresponding 1,3-bis(trimethylsilyl)-1,3,2-diazabora-[3]ferrocenophanes (3)-(8) and the 2,3-bis(dimethylamino)-1,4-bis(trimethylsilyl)-1,4,2,3-diazadibora-[4] ferrocenophane (9). All new complexes were characterised by multinuclear magnetic resonance spectroscopy in solution, and the solid-state molecular structures of the hydride (3), fluoride, chloride (4, 5), and of the phenoxy and phenyl derivatives (7, 8) were determined by X-ray analysis.