850494-65-4Relevant academic research and scientific papers
D-allal- and d-galactal-derived vinyl N-mesylaziridines: Regio- and stereoselectivity in addition reactions of O-, C-, N-, and S-nucleophiles
Di Bussolo, Valeria,Frau, Ileana,Pineschi, Mauro,Crotti, Paolo
, p. 2863 - 2871 (2012/11/13)
The regioselectivity and stereoselectivity were examined of the addition reactions of O-, C-, N- and S-nucleophiles to d-allal- and d-galactal-derived N-mesylaziridines. The ratio of 1,4-regioselectivity (exclusive syn-1,4-addition) to 1,2-regioselectivit
Stereoselective synthesis of 4-(N-mesylamino)-2,3-unsaturated-α-O- glycosides via a new glycal-derived vinyl α-N-(mesyl)-aziridine
Di Bussolo, Valeria,Romano, Maria Rosaria,Pineschi, Mauro,Crotti, Paolo
, p. 1299 - 1302 (2007/10/03)
(Chemical Equation Presented) N-Mesyl aziridine 7α, a new activated vinyl aziridine derived from D-glucal, has been synthesized by cyclization of trans-N,O-dimesylate 6 with t-BuOK in anhydrous benzene. The reaction of 7α with alcohols, phenol, and monosa
