85051-71-4Relevant academic research and scientific papers
Rearrangement of vic-Diol Monoacetates Promoted by Organoaluminium Compounds
Kanemoto, Shigekazu,Morizawa, Yoshitomi,Oshima, Koichiro,Nozaki, Hitosi
, p. 3941 - 3942 (1982)
Treatment of pinacol monoacetate with organoaluminium reagent R3Al caused the rearrangement under uptake of R as a nucleophile on the resulting carbonyl carbon, while R2AlSPh produced the pinacolone itself upon workup.
Synthesis and Ring-Opening Reactions in the 1,3'-Bicyclopropenyl Series
Padwa, Albert,Pulwer, Mitchell J.,Rosenthal, Robert J.
, p. 856 - 862 (2007/10/02)
Several 1,3'-bicyclopropenyl compounds were prepared by treating 1,3,3-trisubstituted cyclopropenes with methyllithium followed by reaction of the lithiate with cyclopropenylium perchlorate derivates.Thermolysis of a sample of 3-methyl-1-(1-methyl-2,3-dip
