850544-46-6

Basic information

• Product Name: N,N-diisopropyl-2-(phenylthio)ferrocenecarboxamide
• CAS NO: 850544-46-6
• Molecular Weight: 421.386
• Mol File: 850544-46-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N,N-diisopropyl-2-(phenylthio)ferrocenecarboxamide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-diisopropyl-2-(phenylthio)ferrocenecarboxamide(850544-46-6)
• EPA Substance Registry System: N,N-diisopropyl-2-(phenylthio)ferrocenecarboxamide(850544-46-6)

Safety Data

• Hazardous Substances Data: 850544-46-6(Hazardous Substances Data)

Upstream product

• 169830-46-0 [(bis(1-methylethyl)amino)carbonyl]ferrocene 
• 882-33-7 diphenyldisulfane 

Downstream Products

• 875476-93-0 (N,N-diisopropylferrocenecarboxamide)S(=O)(phenyl) 

Relevant articles and documents

Protection against peroxynitrite-mediated nitration reaction by intramolecularly coordinated diorganoselenides

A series of intramolecularly Se...X (X = N, O) coordinated diorganoselenides and -sulfides are synthesized by using the heteroatom-directed lithiation route and characterized by multinuclear (1H, 13C, 77Se) NMR, IR spectroscopy, and electrospray mass spectrometry (ES-MS). The intramolecular Se...O interactions in diorganoselenides 26-31 have been studied by multinuclear NMR studies in solution and in the solid state by single-crystal X-ray crystallography. The protection against peroxynitrite-mediated nitration reaction (PN assay) by diorganoselenides/-sulfides (with and without intramolecular coordination) has been evaluated. The PN assay data of diorganoselenides reveal that the selenides 20-22, having a basic amino group (sp3-N donor) in close proximity of selenium, are more active compared to the diorganoselenides 16-19, having an imino group (sp2-N donor), and also show much higher protective action than the unsubstituted diorganoselenides 14 and 15. The diorganoselenides 16-31 were oxidized to corresponding selenoxides 44-59. The redox properties of the selenoxides 13 and 44-59 have been investigated by cyclic voltammetry and potentiometric titration experiments. Two redox potentials for in situ-generated ferrocenyl selenoxides (50, 54-59) were observed. The reduction of selenoxides 13 and 48 to ebselen (2) and selenide 20 with benzenethiol (PhSH) was monitored by ES-MS.