85072-91-9Relevant articles and documents
CYCLOADDITION WITH SIMULTANEOUS ELIMINATION OF TRIPHENYLPHOSPHINE IN THE REACTION OF BETAINES - α-(TRIPHENYLPHOSPHONIO)ALKYLDITHIOCARBOXYLATES - WITH ACTIVATED ACETYLENES
Drozd, V. N.,Vyazgin, A. S.
, p. 1214 - 1218 (2007/10/02)
α-(Triphenylphosphonio)alkyldithiocarboxylates react with acetylenes activated by electron-withdrawing substituents by a mechanism of anionic -cycloaddition with the simultaneous elimination of triphenylphosphine and the formation of 2-alkylidene-1,3-dithioles.