850786-08-2Relevant academic research and scientific papers
Stereoselective access to substituted [(E)- or (Z)-1-(trifluoromethyl)- allyl]amines
Magueur, Guillaume,Crousse, Benoit,Bonnet-Delpon, Daniele
experimental part, p. 1527 - 1534 (2009/04/11)
Hydrometallation reactions, for example, hydroboration and hydroalumination, on [1-(trifluoromethyl)propargyl]amines lead stereoselectively to the corresponding [(Z)- and (E)-1-(trifluoromethyl)allyl]amines in good yields; (Z)- and (E)-allylamines with a free amino group can be obtained in good yields and excellent enantioselectivities from the chiral propargylamines. Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
