85079-99-8Relevant academic research and scientific papers
STEREOSELECTIVE SYNTHESIS OF L-SUGARS OF BIOLOGICAL IMPORTANCE STARTING FROM 4-O-BENZYL-2,3-O-ISOPROPYLIDENE-L-THREOSE AS A CHIRAL BUILDING BLOCK
Mukaiyama, Teruaki,Yamada, Tohru,Suzuki, Keisuke
, p. 5 - 8 (1983)
Biologically important L-sugars 2-deoxy-L-galactose, 3-amino-2,3-dideoxy-L-xylo-hexose, and L-diginose were succesfully synthesized from the homoallyl alcohol, prepared by the stereoselective addition of allylic Sn(IV) reagent to 4-O-benzyl-2,3-O-isopropylidene-L-threose.
4-O-Benzyl-23-O-isopropylidene-L-threose: A useful building block for stereoselective synthesis of monosaccharides
Mukaiyama, Teruaki,Suzuki, Keisuke,Yamada, Tohru,Tabusa, Fujio
, p. 265 - 276 (2007/10/02)
4-O-Benzyl-23-O-isopropylidene-L-threose readily available from L-tartaric acid is a quite useful four-carbon building block for monosaccharide synthesis. The versatility can be reinforced by the coupled use of stereoselective addition reactions where the
