85100-03-4

Upstream product

• 72229-17-5 (+/-)-trans-1-(benzyloxy)but-2-ene oxide 
• 132150-02-8 C₁₆H₃₃AlOSi 
• 85100-02-3 Benzoic acid (1R,2R)-1-benzyloxymethyl-2-(toluene-4-sulfonyloxy)-propyl ester 
• 85100-00-1 Benzoic acid (1R,2R)-1-benzyloxymethyl-2-hydroxy-propyl ester 
• 85200-35-7 (2R,3S)-2-Benzyloxymethyl-3-methyl-oxirane 
• 19164-01-3 ((but-2-en-1-yloxy)methyl)benzene 

Relevant academic research and scientific papers

The opening of trans-2-3-epoxy-1-butanol derivatives with organometallic reagents

The opening of trans-2-3-epoxy-butan-1-ol derivatives with various organometallic reagents was studied to find the best conditions necessary to obtain convenient yields and regioselectivities for their application in natural product synthesis.

SYNTHESIS OF THE ENANTIOMERIC FORMS OF CIS AND TRANS 1-BENZYLOXY-2,3-EPOXY BUTANE AND OF (3S,4S) 4-METHYL-3-HEPTANOL

The C4 erythro and threo diols (7) and (8) are converted either into the chiral epoxides (13) and (15) or into the enantiomers (14) and (16); the epoxide (13) is used as chiral synthon for the preparation of (3S,4S) 4-methyl-3-heptanol (21).