851009-46-6

Upstream product

• 851009-45-5 (5E,7E)-2-(tert-butyldiphenylsilyloxy)-10-(4-methoxybenzyloxy)-7-methyldeca-5,7-dienoic acid methoxy(methyl)amide 
• 151502-81-7 cis-3-dimethyl(1,1-dimethylethyl)silyloxy-1-iodo-1-propene 
• 851009-33-1 (5E,7E)-10-(4-methoxybenzyloxy)-7-methyldeca-5,7-dienoic acid methyl ester 
• 851009-34-2 (5E,7E)-2-hydroxy-10-(4-methoxybenzyloxy)-7-methyldeca-5,7-dienoic acid methyl ester 
• 500702-36-3 (2E)-2-iodo-5-[(4-methoxybenzyl)oxy]pent-2-ene 
• 851009-44-4 (5E,7E)-2-(tert-Butyl-diphenyl-silanyloxy)-10-(4-methoxy-benzyloxy)-7-methyl-deca-5,7-dienoic acid methyl ester 

Relevant academic research and scientific papers

Stereoselective synthesis of the octahydronaphthalene unit of integramycin via an intramolecular Diels-Alder reaction

(Chemical Equation Presented). The racemic cis-decalin core fragment 30 of integramycin was synthesized by a sequence involving a highly diastereoselective intramolecular Diels-Alder reaction of triene 24. A remarkable switch in stereoselectivity occurred