851051-04-2

Basic information

• Product Name: Benzeneacetic acid, (6E)-3-hydroxy-3,7,11-trimethyl-6,10-dodecadienyl ester
• CAS NO: 851051-04-2
• Molecular Formula: C23H34O3
• Molecular Weight: 358.521
• Mol File: 851051-04-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzeneacetic acid, (6E)-3-hydroxy-3,7,11-trimethyl-6,10-dodecadienyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetic acid, (6E)-3-hydroxy-3,7,11-trimethyl-6,10-dodecadienyl ester(851051-04-2)
• EPA Substance Registry System: Benzeneacetic acid, (6E)-3-hydroxy-3,7,11-trimethyl-6,10-dodecadienyl ester(851051-04-2)

Safety Data

• Hazardous Substances Data: 851051-04-2(Hazardous Substances Data)

Upstream product

• 147127-72-8 ((2S,3S)-3-((E)-4,8-dimethylnona-3,7-dien-1-yl)-3-methyloxiran-2-yl)methanol 
• 106-28-5 Farnesol 
• 851050-85-6 (S)-3,7,11-trimethyl-6,10-dodecadiene-1,3-diol 
• 501-53-1 benzyl chloroformate 

Downstream Products

• 851051-02-0 (-)-2-((2S,4aR,8aR)-2,5,5-8a-tetramethyloctahydrochromen-2-yl)ethyl phenylacetate 
• 851050-97-0 (2S,4aS,8aS)-(-)-2-(2,5,5,8a-tetramethyloctahydrochromen-2-yl)ethyl phenylacetate 

Relevant articles and documents

Biomimetic synthesis of acid-sensitive (-)-caparrapi oxide and (+)-8-epicaparrapi oxide induced by artificial cyclases

(Chemical Equation Presented) Asymmetric total syntheses of acid-sensitive (-)-caparrapi oxide (1) and (+)-8-epicaparrapi oxide (2) from farnesol (9) were achieved using Sharptess-Katsuki epoxidation and Lewis acid-assisted chiral Bronsted acid (chiral LBA)-induced polyene cyclization as key steps. Furthermore, (-)-1 could be directly synthesized from (S)-nerolidol (3) and (R)-LBA with 88% ds by reagent control which overcame substrate control, while (-)-2 was obtained from (R)-3 and (R)-LBA with >99% ds by the double-asymmetric induction.