851113-07-0Relevant academic research and scientific papers
Allenyl azide cycloaddition chemistry: Exploration of the scope and mechanism of cyclopentennelated dihydropyrrole synthesis through azatrimethylenemethane intermediates
Feldman, Ken S.,Iyer, Malliga R.,Lopez, Carlos Silva,Faza, Olalla Nieto
, p. 5090 - 5099 (2008/12/20)
(Chemical Equation Presented) Detailed studies of the thermal conversion of 1-azidohepta-3,4,6-trienes into cyclopentennelated dihydropyrroles are presented. High levels of diastereoselectivity and regioselectivity are documented. A mechanistic proposal t
Allenyl azide cycloaddition chemistry. Synthesis of pyrrolidine-containing bicycles and tricycles via the possible intermediacy of azatrimethylenemethane species
Feldman, Ken S.,Iyer, Malliga R.
, p. 4590 - 4591 (2007/10/03)
Thermolysis of 5-azidoallenes bearing a C(1) methyl group and either an aryl ring or an alkene on C(1) furnishes tricyclic (from the aryl substrates) or bicyclic (from the alkenyl substrates) pyrrolidine products following formal H-CN addition across an i
