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85118-07-6

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85118-07-6 Usage

Chemical Properties

white crystals

Check Digit Verification of cas no

The CAS Registry Mumber 85118-07-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,5,1,1 and 8 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 85118-07:
(7*8)+(6*5)+(5*1)+(4*1)+(3*8)+(2*0)+(1*7)=126
126 % 10 = 6
So 85118-07-6 is a valid CAS Registry Number.
InChI:InChI=1/C7H6BFO4/c9-6-3-4(7(10)11)1-2-5(6)8(12)13/h1-3,12-13H,(H,10,11)

85118-07-6 Well-known Company Product Price

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  • Alfa Aesar

  • (A13067)  3,4-Difluorobenzophenone, 98%   

  • 85118-07-6

  • 5g

  • 725.0CNY

  • Detail
  • Alfa Aesar

  • (A13067)  3,4-Difluorobenzophenone, 98%   

  • 85118-07-6

  • 25g

  • 2157.0CNY

  • Detail

85118-07-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 3,4-Difluorobenzophenone

1.2 Other means of identification

Product number -
Other names (3,4-difluorophenyl)-phenylmethanone

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:85118-07-6 SDS

85118-07-6Relevant articles and documents

Palladium-Catalyzed Amide N-C Hiyama Cross-Coupling: Synthesis of Ketones

Idris, Muhammad Aliyu,Lee, Sunwoo

supporting information, p. 9190 - 9195 (2020/11/18)

N-Acylglutarimides and arylsiloxanes reacted in the presence of Pd(OAc)2/PCy3, Et3N·3HF, and LiOAc to provide the corresponding arylketones in good yields. Aryl-, vinyl-, and alkyl-substituted N-acylglutarimides showed good activity in the coupling reactions of arylsiloxanes. The reaction had a broad substrate scope and showed good functional group tolerance. N-Benzoylsuccinimide and N-protected N-phenylbenzamides showed good activities in coupling reactions with phenylsiloxane. The employment of CuF2 as an activor afforded the decarbonylative products at 160 °C.

Suzuki-Miyaura Cross-Coupling of Amides using Well-Defined, Air-Stable [(PR3)2Pd(II)X2] Precatalysts

Li, Guangchen,Ma, Siyue,Szostak, Michal,Zhou, Tongliang

supporting information, (2020/05/26)

A versatile method for the Suzuki-Miyaura cross-coupling of amides using highly active, well-defined, and air-stable Pd?phosphine precatalysts is reported. Most notably, the method represents the first example of using practical and operationally-simple Pd(II)?phosphine precatalysts in the emerging amide bond cross-coupling manifold. The reactions are efficient at 0.10 mol% loading, furnishing biaryl ketones with high chemoselectivity for N?C(O) bond cleavage. This versatile method enables for the first time to achieve Pd?phosphine-catalyzed cross-coupling of amides at ppm loading. This C?N cross-coupling can be used to efficiently furnish pharmaceutical intermediates by orthogonal Pd-catalyzed cross-couplings. We fully expect that operationally-simple [(PR3)2Pd(II)X2] precatalysts as effective triggers for N?C(O) cross-coupling will be of broad synthetic and catalytic interest. (Figure presented.).

Pd-Catalyzed Suzuki–Miyaura Cross-Coupling of Arylboronic Acids and α-Iminonitriles through C–CN Bond Activation

Liu, Kui,Tao, Shou-Wei,Qian, Chun,Zhu, Yong-Ming

supporting information, p. 4769 - 4775 (2018/09/06)

A Pd-catalyzed Suzuki–Miyaura cross-coupling reaction between arylboronic acids and α-iminonitriles has been developed. The reaction proceeds through selective activation of the C–CN bond, tolerates a wide range of substituents, and delivers the versatile ketone products in moderate to excellent yields.

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