851189-15-6

Upstream product

• 108-98-5 thiophenol 
• 62446-93-9 1,2,3,4-tetra-O-acetyl-D-xylopyranose 
• 521304-45-0 phenyl 2,3,4-tri-O-acetyl-1-thio-1-deoxy-D-xylopyranoside 
• 52544-91-9 (2S,3R,4S,5R)-2-(phenylthio)tetrahydro-2H-pyran-3,4,5-triyl triacetate 
• 4049-33-6 tetra-O-acetyl-β-D-xylopyranose 
• 521304-46-1 phenyl 2,3-O-isopropylidene-1-thio-β-D-xylopyranoside 
• 20452-28-2 phenyl 1-thio-β-D-xylopyranoside 
• 521304-58-5 phenyl 4-O-benzyl-2,3-O-isopropylidene-1-thio-β-D-xyloside 

Downstream Products

• 521304-48-3 (2S,3R,4S,5R)-5-Benzyloxy-3,4-bis-(4-methoxy-benzyloxy)-2-phenylsulfanyl-tetrahydro-pyran 
• 521304-50-7 (2S,3R,4S,5R)-2-Benzenesulfinyl-5-benzyloxy-3,4-bis-(4-methoxy-benzyloxy)-tetrahydro-pyran 
• 521304-49-4 (3R,4S,5R)-5-Benzyloxy-2-fluoro-3,4-bis-(4-methoxy-benzyloxy)-tetrahydro-pyran 

Relevant academic research and scientific papers

Silyl migrations in d-xylose derivatives: Total synthesis of a marine quinoline alkaloid

A versatile method for the synthesis of orthogonally protected d-xylose 1-thioethers is described using unusual silyl group migrations which were pivotal in the synthesis of 4,8-dimethyl-6-O-(2′,4′-di-O-methyl- β-d-xylopyranosyl)hydroxyquinoline confirming the structure and absolute configuration of the natural product.

Modifying the regioselectivity of glycosynthase reactions through changes in the acceptor

Successful glycosynthase-mediated reactions have been performed on 6-O-benzyl-, 6-O-(4-nitrobenzyl)-, and 6-O-benzoyl-D-glucopyranose to give 1,2-β- and 1,3-β-D-glycosylated products; 4-O-benzyl-D-xylopyranose gave only a 1,2-β-glycosylated product. A rat

Synthesis of the N-terminus of glycopeptide unit for aeruginosin 205-A

The N-terminus moiety of glycopeptide unit for aeruginosin 205-A has been synthesized.